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Creators/Authors contains: "Shi, Yanshu"

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  1. ; ; ; ; ; ; ; ; ; ; et al (, Nature)
    Free, publicly-accessible full text available February 13, 2026
  2. ; ; ; ; ; (, Small)
    Abstract Propylene is a crucial building block to produce many industrial‐scale chemicals including polypropylene. The separation of propylene from propane to reach the high‐purity levels needed for downstream applications is a difficult task due to the close similarities in their physical properties. The olefin/paraffin separation including that involving propylene mainly relies on highly energy‐intensive distillation processes and accounts for nearly 0.3% of the global energy consumption. The utility of a copper complex supported by a fluorinated bis(pyrazolyl)borate is demonstrated to accomplish the separation of propylene from propane repeatedly, under mild conditions with high selectivity. Complete characterization of a rare, copper(I) propylene complex is also reported including the molecular structure. 
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